Kaichang Li

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Kaichang receives the 2007 "Green Chemistry" Award

Adhesive News Articles

Associate Professor

Department of Wood Science & Engineering

102 Richardson Hall

Oregon State University

Corvallis, Oregon  97331

EMAIL: Kaichang.Li@oregonstate.edu
Phone: (541) 737-8421; Fax:  (541) 737-3385  
   

 

Table of Contents

EDUCATION o  PATENTS
PROFESSIONAL EXPERIENCE HONORS
TEACHING MEMBERSHIP IN PROFESSIONAL SOCIETIES
o  RESEARCH INTERESTS o  PUBLICATIONS
o  CURRENT RESEARCH o  OPPORTUNITIES FOR GRADUATE RESEARCH ASSISTANTSHIPS
o  STUDENT THESES  

Education

Professional Experience
Teaching

WSE 445/545 -- Chemical Wood Processing and Pollution Control

This course covers the basics of the papermaking process. More specifically, the covered contents are as follows: wood and wood chip quality, pulping methods and pulping chemistry, kraft recovery, pulp bleaching methods and bleaching chemistry, pulp processing, paper additives and wet-end chemistry, papermaking, paper and paper properties, and environmental impacts of papermaking. Applications of biotechnology in pulp and paper industry, such as biopulping, biobleaching, and pitch control, will be covered as well. Fall quarter.

WSE 535 -- Polymer Syntesis and Structure

This course will overview various synthetic methods for making polymers. This course also discusses structure of polymer molecules and role of that structure in properties.

Research Interests

Development of formaldehyde-free wood adhesives from renewable natural resources; development and characterization of superior wood-plastic composites; investigation of interfacial chemistry of wood-plastic composites; development of new paper additives from renewable natural resources with biological methods; development of new applications for room temperature ionic  liquids; novel technology for bio-energy, mechanistic studies of lignin biodegradation; development of an environmentally benign pulp bleaching technique; modification of cellulose and lignin for a high-value added product; pulping and pulp bleaching chemistry.  

Current Research

My research programs encompass the following broad areas:  1)  development of formaldehyde-free wood adhesives from renewable natural resources, 2) development and characterization of superior wood-plastic composites, 3) investigation of interfacial chemistry of wood-plastic composites, 4) development of new paper additives from renewable natural resources with biological methods, 5) development of new applications for room temperature ionic liquids, 6) development of pressure sensitive adhesives from renewable materials, 7) development of novel dental adhesives, 8) development of novel dental composite materials.

Development of Formaldehyde-Free Wood Adhesives.  There are two important issues associated with the currently used wood adhesives, phenol-formaldehyde (PF) and urea-formaldehyde  (UF), in the forest products industry:  1)  These synthetic adhesives are petroleum-based, whereas the resources for petroleum are naturally limited; 2)  Hazardous compounds such as formaldehyde may be emitted in the production and the use of wood composites bonded with PF and UF resins.  Our objective for this study is to develop a commercially viable,  formaldehyde-free wood adhesive from renewable natural resources for production of wood composites.  

Inspired by the strong and water-resistant binding of marine organisms such as mussels to rocks and other substances, we are investigating conversion of renewable natural resources such as soy protein, carbohydrates, and lignin to a strong and water-resistant wood adhesives.  At present, one of our formaldehyde-free soy-based adhesives is commercially used for production of interiorly used plywood.  The use of our formaldehyde-free wood adhesives for commercial production of other wood composites such as particleboard is being evaluated at a mill scale.  Click here:  NEWS REPORTS--to read some of news reports about our success of developing commercially viable environmentally friendly adhesives.

Development and Characterization of Superior Wood-Plastic Composites.  We have recently developed superior wood-plastic composites whose strengths are comparable with solid wood.  I have recently been awarded a research grant by a startup company to develop scale-up techniques for commercial production of these superior composites.  I have also been rewarded a research grant for development and characterization of superior wood-rubber composites and novel coupling agents for silica-filled rubber composites.

Investigation of Interfacial Chemistry of Wood-Plastic Composites.  Wood-plastic composites such as wood-filled polypropylene are one of the fastest growing sectors in the wood composites industry.  However, the interface between the wood and the plastic is typically weak and fails to transfer stress between the phases.  Consequently, the full strength of the wood is unavailable to reinforce the plastic.  One solution to this problem is a compatibilizer that bridges the interface and improves the stress transfer between the wood and plastic.  We are developing a superior family of wood-plastic compatibilizers and gaining a better understanding of interfacial chemistry of wood-plastic composites.

Development of New Paper Additives from Plant Proteins with Biological Methods.  This project is to investigate conversion of currently over-supplied wheat gluten and corn protein to various paper additives such and paper dry strength agents and paper wet-strength agents using biological methods.

Development of New Applications for Room Temperature Ionic Liquids.  Room temperature ionic liquids (RTIL) are salt-like compounds that are liquid at or near ambient temperature.  RTILs have ionic character, thus having essentially zero vapor pressure.  They are good solvents for a variety of organic, inorganic and polymeric materials.  More and more reports reveal that RTILs may be used as environmentally  friendly solvents and catalysts for various organic reactions and industrial processes.  My research group, as well as my colleague, Dr.  Michael Milota's research group, are working together to utilize the unique properties of RTILs for reduction of volatile organic compounds from exhaust gas in the drying and hot-press of wood-based products.  We have recently found that RTILs can serve as excellent lubricants for production of wood-plastic composites.  We are exploring new applications of RTILs.

Student Theses

(1)  Jian Huang, M.S., 2007.  Development and characterization of new formaldehyde-free soy flour-based adhesives for making interior plywood.

(2)  Yuan Liu, Ph.D., 2005.  Formaldehyde-free wood adhesives from soybean protein and lignin:  development and characterization.

(3)  Dakai Ren, M.S., 2005, Development of temporary wet strength resins from wheat gluten.

(4)  Yu Geng, Ph.D., 2005, Investigation of new compatibilizer systems for wood-polyethylene composites.

(5)  Cheng Zhang, Ph.D., 2005.  Improved  interfacial adhesion in wood-plastic composites:  development of new compatibilizers.

(6)  Fujun Wang, M.S., 2005.  Henry's law constants for pollutants from the wood industry in room temperature ionic liquids.

(7)  Hartono A. Saputra, M.S., 2004.  The effects of extractives and compatibilizers on the flexural properties of natural fiber-thermoplastic composites.

(8)  Svetlana Peshkova, M.S., 2002.  Development of formaldehyde-free wood adhesives.

 

Patents

Li, K.  Formaldehyde-free adhesives and lignocellulosic composites made from the adhesives, U.S. Provisional Patent Application No. 60/538,932.  Application data, January 22, 2004.

Li, K.  and Geng, X.  Adhesive compositions and methods of using and making the same.   US patent # 7,265,169.  Issue date, September 4, 2007

Li, K.  Formaldehyde-free lignocellulosic adhesives and composites made from the adhesives.  U.S. Patent No. 7,252,735.  Issue date, August 7 2007.

Li, K.  and Liu, Y.  Modified protein adhesives and lignocellulosic composites made from the adhesives. U.S. Patent No. 7,060,798. Issue date, June 13, 2006.

Honors

Emerging Faculty Scholar Award, Oregon State University Chapter of the Honor Society of Phi Kappa Phi, May 2002.

Archer Daniels Midland Award for Best Paper in Engineering/Technology in 2004 by American Oil Chemists' Society (Li, K., S. Peshkova, and X. Geng), 2004.  Investigation of soy protein-kymene adhesive systems for wood composites.  J. Am. Oil Chem. Soc. 81(5):487-491.

2007 Presidential Green Chemistry Challenge Award.

Memberships in Professional Societies
Publications

 

Catal, T., K. Li, H. Bermek, and H. Liu. 2008. Electricity production from twelve monosaccharides using microbial fuel cells. J. Power Sources:in press.

Huang, J., and K. Li. 2008. A new soy flour-based adhesive for making interior type II plywood. J. Am. Oil Chem. Soc.:in press.

Li, K., and J. Z. Lu. 2008. New Insights into the Mechanisms of Compatibilization in Wood-Plastic Composites, In press. In T. Q. Hu (ed.), Characterization of lignocellulosic materials, vol. Chapter 16. Blackwell Publishing.

Saputra, H. A., J. Simonsen, and K. Li. 2007. Effects of compatibilizers on the flexural properties of grass straw–polyethylene composites. J. Biobased Mat. Bioenergy 1(1):137-142.

Li, K., and K. Zhou. 2007. Room Temperature Ionic liquids as Lubricants for Wood-Polyethylene Composites, p. 168-181. In D. S. Argyropoulos (ed.), ACS Symposium Series 954 -- Materials, Chemicals and Energy from Forest Biomass. American Chemical Society, Washington, DC.

Wang, F., M. R. Milota, P. Mosher, K. Li, and M. Yankus. 2007. Henry’s Law constants for methanol and α-pinene in ionic liquids. Wood Fiber Sci. 39(3):434-442

Milota, M., P. Mosher, and K. Li. 2007. VOC and HAP removal from dryer exhaust gas by absorption into ionic liquids. Forest Prod J. 57(5):73-77.

Lu, J. Z., T. W. Doyle, and K. Li. 2007. Preparation and characterization of wood-(nylon 12) composites. J. Appl. Polym. Sci. 103(1):270-276.

Liu, Y., and K. Li. 2007. Development and characterization of adhesives from soy protein for bonding wood. Int. J. Adhesion Adhesives 27:59-67.

Liu, Y. and K. Li.  2006.  Preparation and characterization of demethylated lignin-polyethylenimine adhesives.  J. Adhesion 82(6):593-605.

Geng, X. and K. Li.  2006.  Investigation of wood adhesives from kraft lignin and polyethylenimine.  J. Adhesion Sci. Technol. 20(8):847-858.

Geng, Yu., K. Li and J. Simonsen.  2006.  Further investigation of polyaminoamide-epichlorohydrin/stearic anhydride compatiblizer system for wood-polyethylene composites.  J. Appl. Polym. Sci. 99(3):712-718.

Zhang, C., K. Li and J. Simonsen.  2006.  Terminally functionalized polyethylenes as compatibilizers for wood-polyethylene composites.  Polym. Engr. Sci. 46(1):108-113.

Geng, Y., K. Li, and J. Simonsen.  2005. A combination of poly(diphenylmethane diisocyanate) and stearic anhydride as a novel compatibilizer for wood-polyethylene composites. J. Adhesion Sci. Technol. 19(11):987-1001.

Ren, D., and K. Li. 2005. Development of wet strength additives from wheat gluten. Holzforschung, 59:598-603.

Geng, Y., K. Li, and J. Simonsen.  2005. A commercially viable compatibilizer system for wood-polyethylene composites. J. Adhesion Sci. Technol. 19(15):1363-1373.

Li, K., and X. Geng. 2005. Formaldehyde-free wood adhesives from decayed wood. Macromol. Rapid Commun. 26:529-532.

Zhang, C., K. Li, and J. Simonsen.  2004. Improvement of interfacial adhesion between wood and polypropylene in wood-polypropylene composites. J. Adhesion Sci. Technol. 18(14):1603-1612.

Saputra, H., J. Simonsen, and K. Li.  2004. Effect of extractives on the flexural properties of wood/plastic composites. Compos. Interfaces 11(7):515-524.

Liu, Y., and K. Li.   2004. Modification of soy protein for wood adhesives using mussel protein as a model: the influence of a mercapto group. Macromol. Rapid Commun. 25:1835-1838.

Bermek, H., I. Gülseren, K. Li, H. Jung, and C. Tamerler.   2004. The effect of fungal morphology on ligninolytic enzyme production by a recently isolated wood-degrading fungus Trichophyton rubrum LSK-27. World J. Microbiol. Biotechnol. 20:345-349.

Bermek, H., H. Yazici, M. H. Öztürk, C. Tamerler, H. Jung, K. Li, K. M. Brown, H. Ding, and F. Xu.   2004. Purification and characterization of manganese peroxidase from wood-degrading fungus Trichophyton rubrum LSK-27. Enzym. Microb. Technol. 35:87-92.

Geng, X., H. Jung, and K. Li.   2004. Degradation of wood and pulp by three fungi, Pycnoporus cinnabarinus, Trichophyton rubrum LKY-7 and Trichophyton rubrum LSK-27, p. 139-151. In B. C. Saha and K. Hayashi (ed.), ACS Symposium Series 889 Lignocellulose biodegradation. American Chemical Society, Washington DC.

Geng, X., K. Li, and F. Xu.   2004. Investigation of hydroxamic acids as laccase-mediators for pulp bleaching. Appl. Microbiol. Biotechnol.

64(4:493-496.

Geng, Y., K. Li, and J. Simonsen.   2004. Effects of a new compatibilizer system on the flexural properties of wood-polyethylene composites. J. Appl. Polym. Sci. 91:3667-3672.

Li, K., and X. Geng. 2004. Investigation of formaldehyde-free wood adhesives from kraft lignin and a polyaminoamide-epichlorohydrin resin. J. Adh. Sci. Technol. 18(4):427-439.

Li, K., X. Geng, J. Simonsen, and J. J. Karchesy. 2004. Novel wood adhesives from condensed tannins and polyethylenimine. Int. J. Adhesion Adhes. 24(4):327-333.

Li, K., S. Peshkova, and X. Geng. 2004. Investigation of soy protein-kymene adhesive systems for wood composites. J. Am. Oil Chem. Soc. 81(5):487-491.

Li, X., Y. Geng, J. Simonsen, and K. Li. 2004. Application of ionic liquids for electrostatic control in wood. Holzforschung 58(3):280-285.

Rogers, J., X. Geng, and K. Li. 2004. Soy-based adhesives with 1,3-dichloro-2-propanol as curing agent. Wood Fiber Sci. 36(2):186-194.

Freitag, C. M., K. Li, and J. J. Morrell. 2003. Potential for the use of hydroxylamine derivatives as wood preservatives. Forest Prod. J. 53(7/8):77-79.

Geng, X., and K. Li.  2003. Deinking of recycled mixed office paper using two endo-glucanases, CelB and CelE, from the anaerobic fungus Orpinomyces PC2. TAPPI J. 2(6):29-32.

Geng, X., K. Li, I. A. Kataeva, X. Li, and L. G. Ljungdahl. 2003. Effects of two cellobiohydrolases, Cbha and CelK, from Clostridium thermocellum on deinking of recycled mixed office paper. Progress in Paper Recycling 12(3):6-10.

Li, K. 2003. The role of enzymes and mediators in lignocellulose degradation, p. 196-209. In B. Goodell, D. Nicholas, and T. Schultz (ed.), ACS Symposium Series 845, Wood deterioration and preservation, Advances in our changing world. American Chemical Society, Washington, DC.

Zhang, C., K. Li, and J. Simonsen. 2003. A novel wood-binding domain of a wood-plastic coupling agent: development and characterization. J. Appl. Polm. Sci. 89(4):1078-1084.

Peshkova, S., and K. Li. 2003. Investigation of poly(4-vinylphenol) as a wood adhesive. Wood Fiber Sci. 35(1):41-48.

Peshkova, S., and K. Li. 2003. Investigation of chitosan-phenolics system as wood adhesives. J. Biotechnol. 102(2):199 - 207.

Geng, X., and K. Li. 2002. Degradation of non-phenolic lignin by the white-rot fungus Pycnoporus cinnabarinus. Appl. Microbiol. Biotechnol. 60:342-346.

Liu, Y., and K. Li. 2002. Chemical modification of soy protein for wood adhesives. Macromol. Rapid Commun. 23(13):739-742.

Bermek, H., K. Li, and K.-E. L. Eriksson. 2002. Studies on inactivation and stabilization of manganese peroxidase from Trametes versicolor. Progress in Biotechnology 21:141-149.

Bermek, H., K. Li, and K.-E. L. Eriksson. 2002. Studies on mediators of manganese peroxidase for bleaching of wood pulps. Bioresource Technology 85:249-252.

Li, K., and X. Xu. 2002. Effects of a cellulose binding domain on deinking of recycled mixed office paper. Progress in Paper Recycling 11(2):9-13.

Jung, H., F. Xu, and K. Li. 2002. Purification and Characterization of Laccase from Wood-degrading Fungus Trichophyton rubrum LKY-7. Enzyme and Microbial Technology 30:161-168.

Xu, F., K. Li, and T. J. Elder. 2002. N-hydroxy mediated laccase biocatalysis: recent progress on its mechanism and future prospect of its application. Progress in Biotechnology 21:89-104.

Xu, F., H. J. Deussen, B. Lopez, L. Lam, and K. Li. 2001. Enzymatic and electrochemical oxidation of N-hydroxy compounds. Redox potential, electron-transfer kinetics, and radical stability. Eur. J. Biochem. 268(15):4169-4176.

Li, K., P. S. Horanyi, R. Collins, R. S. Phillips, and K. L. Eriksson. 2001. Investigation of the role of 3-hydroxyanthranilic acid in the degradation of lignin by white-rot fungus Pycnoporus cinnabarinus. Enzyme Microb. Technol. 28(4-5):301-307.

Li, K., N. G. Prabhu, D. A. Cooper, F. Xu, T. Elder, and K.-E. L. Eriksson. 2001. Development of New Laccase-mediators for Pulp Bleaching, p. 400-412. In D. S. Argyropoulos (ed.), ACS symposium series 785, Oxidative Delignification Chemistry: Fundamentals and Catalysis. American Chemical Society, Washington DC.

Bermek, H., K. Li, and K.-E. L. Eriksson. 2000. Pulp bleaching with manganese peroxidase and xylanase: a synergistic effect. Tappi J. 83(10):69.

Xu, F., J. J. Kulys, K. Duke, K. Li, K. Krikstopaitis, H. J. Deussen, E. Abbate, V. Galinyte, and P. Schneider. 2000. Redox chemistry in laccase-catalyzed oxidation of N-hydroxy compounds. Appl. Environ. Microbiol. 66(5):2052-2056.

Li, K., P. Azadi, R. Collins, J. Tolan, J. S. Kim, and K.-E. L. Eriksson. 2000. Relationship between activities of xylanases and xylan structures. Enzyme Microb. Technol. 27:89-94.

Li, K., R. Collins, and K.-E. L. Eriksson.   2000. Removal of dyes from recycled paper. Progress in Paper Recycling November:37-43.

Li, K., and K.-E. L. Eriksson. 2000. The importance of a laccase/mediator system in lignin degradation. Ind. J. Microbiol. 40:149-261.

Li, K., and R. F. Helm. 2000. Neolignan skeletons and benzodioxanes through chiral aryl alkyl ether formation. Holzforschung 54(6):597-603.

Li, K., F. Xu, and K. E. Eriksson. 1999. Comparison of fungal laccases and redox mediators in oxidation of a nonphenolic lignin model compound. Appl. Environ. Microbiol. 65(6):2654-60.

Li, K., R. F. Helm, and K.-E. L. Eriksson. 1998. Mechanistic studies of the oxidation of a non-phenolic lignin model compound by the laccase/1-hydroxybenzotriazole redox system. Biotechnol. Appl. Biochem. 27:239-243.

Bermek, H., K. Li, and K.-E. L. Eriksson.   1998. Laccase-less mutants of the white-rot fungus Pycnoporus cinnabarinus cannot delignify kraft pulp. J. Biotechnol. 66(2-3):117-124.

Helm, R. F., M. Toikka, K. Li, and G. Brunow. 1997. Lignin glycosides: preparation and optical resolution. J. Chem. Soc. Perkin Trans 1:533-537.

Li, K., and R. F. Helm.  1996. Approaches to synthetic neolignans. J. Chem. Soc. Perkin Trans 1:2425-2426.

Li, K., and R. F. Helm.   1995. Synthesis and rearrangement reactions of ester-linked lignin-carbohydrate model compounds. J. Agric. Food Chem. 48:2098-2103.

Li, K., and R. F. Helm. 1995. A practical synthesis of methyl 4-O-methyl-a-D-glucopyranosiduronic acid. Carbohydr. Res. 273:249-253.

Helm, R. F., and K. Li. 1995. Complete the threo stereospecificity for the preparation of b-O-4 lignin model dimers. Holzforschung 49:533-536.

 

 

Opportunities for Graduate Research Assistantships

Graduate Research Assistantships are currently available for qualified students. I would prefer the prospective graduate students to have backgrounds in one of the following areas: polymer science including polymer chemistry, polymer physics, and polymer processing, composite materials science, organic chemistry, wood chemistry and biochemistry.

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